Oxygen Vacancy-Enriched Bi2SeO5 Nanosheets with Dual Mechanism for Ammonium-Ion Batteries

Ammonium ions feature a light molar mass and small hydrated radius, and the interesting interaction between NH4+ and host materials has attracted widespread attention in aqueous energy storage, while few studies focus on high-performance NH4+ storage anodes. Herein, we present a high-performance inset-type anode for aqueous ammonium-ion batteries (AIBs) based on Bi2SeO5 nanosheets. A reversible NH4+/H+ co-intercalation/deintercalation accompanied by hydrogen bond formation/breaking and a conversion reaction mechanism in layered Bi2SeO5 is proposed according to ex situ characterizations. Accordingly, the optimized Bi2SeO5 anode has a high reversible capacity of 341.03 mAh g-1 at 0.3 A g-1 in 1 M NH4Cl electrolyte and an impressive capacity retention of 86.7% after 7000 cycles at 3 A g-1, which is related to the existence of oxygen vacancies that enhance ion/electron transfer and promote the formation of hydrogen bonds between NH4+ and the host material. When the rocking-chair ammonium-ion battery is assembled using a MnO2 cathode, the device delivers an ultrahigh capacity of 140.73 mAh g-1 at 0.15 A g-1 and energy density of 207.13 Wh kg-1 at the power density of 2985.07 W kg-1. This work provides a promising strategy for designing high-performance anodes for next-generation AIBs.