Fine‐Tuning Conformation of PEDOT Chains Enables Simultaneously Enhanced Conductivity, Work Function, Transmittance, and Waterproofness in PEDOT:PSS Interlayer for Highly Efficient and Stable Organic Photovoltaics

Abstract Poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is widely utilized as the hole transport layer (HTL) inorganic photovoltaics (OPVs) because of its low‐temperature solution processing peculiarity, high optical transmittance, and excellent mechanical flexibility. However, the core–shell structure of PSS coated PEDOT results in relatively low conductivity, work function, transmittance and waterproofness of PEDOT:PSS interlayer, limiting the photovoltaic performance and stability of OPVs. Here, the conformation of PEDOT chains are regulated from helical benzoyl to linear quinone structure via incorporation of 2D Cd 0.85 PS 3 Li 0.15 H 0.15 dopant into the conventional PEDOT:PSS interlayer, promoting an interpenetrating network structure in PEDOT:PSS interlayer and forming an efficient hole transport channel from active layer to ITO electrode. Such features significantly improve the electrical conductivity, work function, and transmittance of PEDOT:PSS interlayer. In consequence, the maximum power conversion efficiency (PCE) of D18:L8‐BO, PBDB‐T:ITIC, as well as PTzBI‐dF:L8‐BO based OPVs ameliorated from 18.37%, 8.94%, and 15.80% to 19.26%, 10.00%, and 16.83%, respectively. The application of Cd 0.85 PS 3 Li 0.15 H 0.15 doping PEDOT:PSS strategy demonstrates great potential for the development of strongly conductive, large‐work‐function, highly transparent, and excellent‐waterproof PEDOT:PSS interlayer toward highly efficient and stable OPVs.