SiC whisker/AgNWs/TPU composite film with asymmetric structure for low‐reflection electromagnetic interference shielding

Abstract The design and preparation of lightweight and flexible electromagnetic interference (EMI) shielding composites with high efficiency and low reflection are critical to the electronic field. First, silver nanowires (AgNWs) were vacuum filtered on the electrospun thermoplastic polyurethane (TPU) fibrous film. Then, by combining the adhesive with the electrospun silicon carbide nanowhisker (SiCnw) @TPU composite fibrous film, the asymmetric EMI shielding composite films with high electromagnetic shielding efficiency (EMI SE) and low incident power were obtained. The lower AgNWs‐TPU layer provides the primary EMI SE, and the upper SiCnw@TPU fibrous film is used for electromagnetic wave absorption. This unique asymmetric structure, the synergistic effect of SiCnw's particular absorbing function and the excellent conductivity of the AgNWs layer make the film show high overall SE (SE T = 55.18 dB). In order to improve the absorption effect of the composite film, the number of layers of SiCnw@TPU was adjusted, resulting in a final reflection coefficient value as low as 0.55. This work proposes a new strategy for developing EMI shielding composite films with high efficiency and low reflection, serving as a reference.