阳极
电解质
材料科学
电池(电)
纳米技术
碱金属
化学工程
钾
纳米颗粒
多孔性
动力学
电化学
离子
化学
电极
复合材料
冶金
热力学
物理化学
物理
工程类
有机化学
功率(物理)
量子力学
作者
Weihao Xia,Fengjun Ji,Yunzhuo Liu,Zhen Han,Kaikai Li,Jingyu Lu,Wei Zhai,Deping Li,Lijie Ci
标识
DOI:10.1016/j.scib.2024.07.046
摘要
Alloying-type anode materials are considered promising candidates for next-generation alkali-ion batteries. However, they face significant challenges owing to severe volume variations and sluggish kinetics, which hinder their practical applications. To address these issues, we propose a universal synthetic strategy, which can realize the facile synthesis of various alloying-type anode materials composed of a porous carbon matrix with uniformly embedded nanoparticles (Sb, Bi, or Sn). Besides, we construct the interactions among active materials, electrolyte compositions, and the resulting interface chemistries. This understanding assists in establishing balanced kinetics and stability. As a result, the fabricated battery cells based on the above strategy demonstrate high reversible capacity (515.6 mAh g
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