化石燃料
氮气
化学
环境科学
有机化学
业务
废物管理
工程类
作者
Jingguang G. Chen,Richard M. Crooks,Lance C. Seefeldt,Kara L. Bren,R. Morris Bullock,Marcetta Y. Darensbourg,Patrick L. Holland,Brian M. Hoffman,Michael J. Janik,Anne K. Jones,Mercouri G. Kanatzidis,Paul W. King,Kyle M. Lancaster,Sergei V. Lymar,Peter H. Pfromm,William F. Schneider,Richard R. Schrock
出处
期刊:Science
[American Association for the Advancement of Science (AAAS)]
日期:2018-05-24
卷期号:360 (6391)
被引量:2190
标识
DOI:10.1126/science.aar6611
摘要
Transforming nitrogen without carbon How much carbon does it take to make nitric acid? The counterintuitive answer nowadays is quite a lot. Nitric acid is manufactured by ammonia oxidation, and all the hydrogen to make ammonia via the Haber-Bosch process comes from methane. That's without even accounting for the fossil fuels burned to power the process. Chen et al. review research prospects for more sustainable routes to nitrogen commodity chemicals, considering developments in enzymatic, homogeneous, and heterogeneous catalysis, as well as electrochemical, photochemical, and plasma-based approaches. Science , this issue p. eaar6611
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