拓扑(电路)
金属有机骨架
化学
锆
方解石
金属
介孔材料
溶剂
晶体工程
纳米技术
晶体结构
结晶学
无机化学
沸石
催化作用
材料科学
有机化学
超分子化学
吸附
组合数学
数学
作者
Tian‐Fu Liu,Nicolaas A. Vermeulen,Ashlee J. Howarth,Peng Li,Amy A. Sarjeant,Joseph T. Hupp,Omar K. Farha
标识
DOI:10.1002/ejic.201600627
摘要
Gaining control over the assembly of mesoporous Zr‐based metal–organic frameworks (MOFs) with modifiable metal nodes remains a challenge. The the topology is intriguing, particularly if considering postsynthetic modification, as it presents large sodalite‐like cages surrounded by 12 interconnected 1D channels that allow for efficient diffusion of guest molecules throughout the structure. Herein, we demonstrate the first Zr MOF with the topology, NU‐1200, which was synthesized by controlling the geometry of the organic building unit. In addition, by using NU‐1200 as a platform, we perform solvent‐assisted metal incorporation to form single‐site metalated nodes, a process that is characterized by single‐crystal X‐ray diffraction.
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