光催化
可见光谱
材料科学
光化学
催化作用
异质结
带隙
电化学
离子液体
降级(电信)
兴奋剂
纳米技术
化学工程
化学
光电子学
有机化学
电极
物理化学
计算机科学
电信
工程类
作者
Zhuomin Qiang,Ximeng Liu,Feng Li,Taihai Li,Meng Zhang,Harishchandra Singh,Marko Huttula,Wei Cao
标识
DOI:10.1016/j.cej.2020.126327
摘要
The Bi-based hierarchical multi-component photocatalytic system is an important player in energy and environmental catalysis due to its full-spectrum light absorption and stable separation of photo-generated charges. In this study, a novel family of iodine doped Bi2O2CO3/Bi2WO6 heterojunctions was successfully developed by a facile ionic liquid assisted solvothermal method. A visible light photocatalytic H2 production rate of 664.5 μmol g−1 h−1 (0.3I-Bi2O2CO3/Bi2WO6 with 3% Pt) has been durably obtained, much higher than those of pristine and undoped counterparts. The photocatalysts are also capable for persistent pollutant and dye degradation. Through electrochemical and spectroscopic tests and density functional theory calculation, the enhanced photocatalytic activity is attributed to formation of the Z-scheme photocatalyst. Therein, the lowered and indirect bandgap and heterojunctional band alignment spontaneously benefit visible light harvesting, electron-hole pair separation, and proton reduction. Besides a facile synthesis for effective photocatalysis, the Z-scheme mechanism is hoped to facilitate the design and realization of similar systems for photocatalytic H2 evolution and organic hazards decontamination.
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