Determination of trace bisphenols in functional beverages through the magnetic solid-phase extraction with MOF-COF composite

Abstract In this study, a novel porous composite (Fe3O4@TAPB-COF@ZIF-8) consisting of metal–organic and covalent organic frameworks was developed and applied to the magnetic solid-phase extraction (MSPE) of bisphenols. The extraction parameters such as the extraction time, solution pH, amounts of adsorbent, and ionic strength were investigated to obtain the best extraction conditions. By optimizing the MSPE, a convenient and sensitive analytical method was established in combination with high-performance liquid chromatography. The method achieved low detection limits (0.04–0.05 ng mL−1), wide linear range (0.25–1000 ng mL−1), good repeatability (1.20–4.30%), good reproducibility (1.34–4.03%), and satisfactory recoveries of four functional beverages (66.2–116.6%).