A Glass‐Ceramic with Accelerated Surface Reconstruction toward the Efficient Oxygen Evolution Reaction

Abstract The effective non‐precious metal catalysts toward the oxygen evolution reaction (OER) are highly desirable for electrochemical water splitting. Herein, we prepare a novel glass‐ceramic (Ni 1.5 Sn@triMPO 4 ) by embedding crystalline Ni 1.5 Sn nanoparticles into amorphous trimetallic phosphate (triMPO 4 ) matrix. This unique crystalline‐amorphous nanostructure synergistically accelerates the surface reconstruction to active Ni(Fe)OOH, due to the low vacancy formation energy of Sn in glass‐ceramic and high adsorption energy of PO 4 3− at the V O sites. Compared to the control samples, this dual‐phase glass‐ceramic exhibits a remarkably lowered overpotential and boosted OER kinetics after surface reconstruction, rivaling most of state‐of‐the‐art electrocatalysts. The residual PO 4 3− and intrinsic V O sites induce redistribution of electron states, thus optimizing the adsorption of OH* and OOH* intermediates on metal oxyhydroxides and promoting the OER activity.