Synthesis and performance characteristics of a new ecofriendly crust-dust suppressant extracted from waste paper for surface mines

原材料 扫描电子显微镜 热重分析 热重分析 化学工程 羧甲基纤维素 材料科学 水溶液 化学 废物管理 复合材料 冶金 有机化学 工程类
作者
Shuailong Li,Gang Zhou,Zongqi Liu,Naiguo Wang,Zunyi Wei,Wei Liu
出处
期刊:Journal of Cleaner Production [Elsevier BV]
卷期号:258: 120620-120620 被引量:146
标识
DOI:10.1016/j.jclepro.2020.120620
摘要

Due to production technologies such as blasting, transportation, and loading, large quantities of dust are produced in surface mines. This dust not only pollutes the environment but also restricts the development of coal mining enterprises. This work aims to use waste paper as raw material for the efficient extraction of cellulose, in which waste materials can be converted to useable materials. This work can broaden the sources of raw materials and provide new methods for the efficient preparation of dust suppressants. As a matrix, sodium carboxymethyl cellulose is a novel crust-dust suppressant that is synthesized by graft copolymerization with polyvinylalcohol and N-vinylpyrrolidone in this study. The results of experiments revealed the high purity of sodium carboxymethylcellulose prepared in flotation for 20 min, the degree of substitution DS > 0.8, and the viscosity of 2% aqueous solution>300 mPa s, which can satisfy the requirements of the experiments. The microscopic reaction and structure of the product are analyzed by infrared spectrometry, scanning electron microscopy and thermogravimetry, and the microscopic mechanism of a crust-dust suppressant is investigated. The reaction process and structural characteristics of the product were analyzed by infrared spectroscopy and scanning electron microscopy, and the product reaction process and final structure were deduced. Thermogravimetric experiments showed that the product had strong thermal stability and ensured the performance of the product during use. This paper reveals the combination of dust suppressants and coal via molecular dynamics simulation. The product performance experiments show that the product has a high shell strength of 98 HA, satisfactory freeze-thaw resistance and high temperature resistance, permeability higher than 15 mm/min, and dust suppression rate of approximately 88% when the wind speed reaches 15 m*s−1 and it can degrade without pollution. In general, the product can effectively suppress coal dust and other forms of dust.
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