Hierarchical Phosphide-Based Hybrid Anodes for High-Performance Lithium-Ion Batteries

Transition metal phosphides (TMPs) have emerged as promising anode materials for lithium-ion batteries (LIBs). However, their poor intrinsic conductivity and significant volume changes result in slow redox kinetics and structural collapse during cycling, which hinder their practical application. Here, a hierarchical hybrid anode is synthesized by evenly dispersing Ni2P particles with N-doped carbon encapsulation on Co(OH)2 nanosheets (Co(OH)2/Ni2P@N–C). This distinctive hybrid structure enhances electron/ion conductivity and reduces the Li+ transport distance, thereby boosting LIB performance. The hierarchical Co(OH)2/Ni2P@N–C hybrid anode delivers a high reversible capacity of 610 mAh g–1 at 0.05 A g–1 and exhibits exceptional long-term stability. This approach could pave the way for the development of high-performance LIBs and provide crucial guidance for designing high-energy-density anodes based on TMPs.