Single and Competitive Adsorption of Naphthalene, Phenanthrene, and Pyrene on Polystyrene Nanofibers

In this investigation, polystyrene (PS) nanofibers were prepared by electrospinning for the adsorption of naphthalene (Nap), phenanthrene (Phe), and pyrene (Pyr) from an aqueous solution. Surface morphology and physicochemical characteristics of PS nanofibers were analyzed using Fourier transform infrared spectroscopy (FT-IR) and point-of-zero-charge calorimetry (pH_pzc). The effects of pH, ion concentration, and temperature on the adsorption were also investigated. The adsorption mechanism of target pollutants on PS nanofibers was investigated by a batch adsorption method. The adsorption kinetic studies showed that the adsorption of the three polycyclic aromatic hydrocarbons (PAHs) on PS nanofibers conformed to the pseudo-second-order kinetic model in both single and ternary systems. Meanwhile, in a single system, the three PAHs adsorbed on nanofibers were controlled by both intraparticle diffusion and liquid film diffusion, whereas the adsorption of Nap in a ternary system was controlled mainly by intraparticle diffusion, and the adsorption of Phe and Pyr was controlled mainly by liquid film diffusion. The isotherm data indicated that the Freundlich model performed better than the Langmuir model for the adsorptions of Nap, Phe, and Pyr on PS nanofibers in both the single system and the ternary system. Due to competitive adsorption, the adsorption capacities of Nap and Pyr on PS nanofibers decreased from 105.816 and 19.098 mg g^-1 in the single system to 23.626 and 12.126 mg g^-1 in the ternary system, but the adsorption of Phe was not affected. π-π interactions and pore filling may be jointly involved in the adsorption of PAHs on PS nanofibers.