Preparation and characterization of smart indicator films based on gellan gum/modified black rice anthocyanin/curcumin for improving the stability of natural anthocyanins

In order to improve the stability of natural anthocyanins in intelligent packaging materials, this work first modified black rice anthocyanins (BRA) by acylation with acetic acid, then modified the acylated BRA by co-coloring with different ratios of curcumin (CUR), and finally added the mixed indicator to gellan gum (GG) to develop intelligent packaging films with good stability. The UV spectroscopy results showed that acetic acid had successfully modified the BRA, while the thermal, photostability and pH stability of the modified black rice anthocyanin (MBRA) were significantly enhanced. The indicators of BRA, MBRA and MBRA mixed with CUR showed excellent pH sensitivity in different buffer solutions. The SEM, FT-IR and XRD results indicated apparent crystalline aggregates on the surface of the films added with a high concentration of CUR. Compared with GG-BRA film, GG-MBRA film improved all properties except for antioxidant performance. Notably, the GG-MBRA/CUR series composite films exhibited significant improvements over the GG-BRA and GG-MBRA films in terms of optical characteristics, mechanical properties, water vapor barrier, oxidation resistance, and color stability; meanwhile, all films exhibited excellent pH sensitivity. Considering all the properties of the films, GG-MBRA/CUR3 film has tremendous potential as a smart indicator film for improving freshness accuracy.