Catalytic regio- and stereoselective silicon–carbon bond formations on unsymmetric gem-difluorocyclopropenes by capture of silyl metal species

A highly regioselective silylation of unsymmetric gem -difluorocyclopropenes was achieved by the capture of in-situ formed silyl metal intermediates, which gave structurally diverse silyldifluorocyclopropanes with good yields and stereoselectivity.