化学
羧化
电催化剂
纳米技术
催化作用
电化学
组合化学
生化工程
有机化学
电极
工程类
物理化学
材料科学
出处
期刊:Advances in Catalysis
日期:2022-01-01
卷期号:: 63-93
标识
DOI:10.1016/bs.acat.2022.07.002
摘要
The development of electrochemical methods for the carboxylation of a variety of substrates to form new C–CO2 bonds has been an area of interest for a number of years and is a powerful way to construct such a bond, often negating the use of water sensitive/pyrophoric reagents (e.g. metal halogen exchange with alkyl lithium compounds). In this review we will examine the breadth of carboxylation reactions available and the type of electrosynthetic cell and catalyst required to carry out the transformation. Traditionally many of these reactions were carried out using sacrificial magnesium/aluminum or zinc anodes, but recent developments have enabled the circumvention of these non-sustainable approaches and have opened the door toward further development of continuous flow processes. These developments have run alongside the increased availability of standardized batch and flow electrochemical systems now available to the synthetic chemist. Competition between the areas of photocatalysis and electrocatalysis through comparative reactivity of single electron transfer processes has driven many of the new innovations in this exciting area of research.
科研通智能强力驱动
Strongly Powered by AbleSci AI