Distorted B/O-containing nanographenes with tunable optical properties

We report the synthesis of two B/O-containing nanographenes, which feature the fusion of three or six planar B/O-heterocycles onto one hexa-peri-hexabenzocoronene π-framework. Incorporation of the B/O-heterocycles not only leads to distorted geometries, but also modulates the electronic structures and results in gradually red-shifted absorptions and fluorescence.