材料科学
丙烯酸酯
光引发剂
单体
光致聚合物
紫外线固化
傅里叶变换红外光谱
高分子化学
高折射率聚合物
涂层
折射率
热重分析
固化(化学)
聚合物
复合材料
化学工程
光电子学
工程类
作者
Jin-Seung Kim,Bong-Sang Cho,Jeong-Ohk Kweon,Seok Kyun Noh
标识
DOI:10.1016/j.porgcoat.2014.05.013
摘要
We synthesized UV-curable di-functional sulfur-containing thioacrylate and thiourethane acrylate with high refractive indices. The structures of monomers were confirmed by nuclear magnetic resonance spectroscopy (NMR) and Fourier transform infrared spectroscopy (FT-IR). The formulation of UV-curable coating film was prepared by thioacrylate monomer, thiourethane acrylate monomer, α-hydroxy-α-methylpropiophenone as the photoinitiator, and bisphenol A epoxy acrylate as the oligomer. The cured coating films were investigated using thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA), Taber abraser tests, transmittance, and refractive index. The value of refractive index for all coating films increased after UV-curing. Transparent, photocurable coating films with high abrasion resistance were prepared. The monomers showed high refractive index. The refractive indices of synthesized monomers (thioacrylate and thiourethane acrylate monomer) are 1.623 and 1.577, respectively.
科研通智能强力驱动
Strongly Powered by AbleSci AI