Phosphorous and selenium tuning Co-based non-precious catalysts for electrosynthesis of H2O2 in acidic media

Electrosynthesis of hydrogen peroxide (H2O2) is an on-site method that enables independent distribution applications in many fields due to its small-scale and sustainable features. The crucial point remains developing highly active, selective and cost-effective electrocatalysts. The electrosynthesis of H2O2 in acidic media is more practical owing to its stability and no need for further purification. We herein report a phosphorus and selenium tuning Co-based non-precious catalyst (CoPSe) toward two-electron oxygen reduction reaction (2e– ORR) to produce H2O2 in acidic media. The starting point of using both P and Se is finding a balance between strong ORR activity of CoSe and weak activity of CoP. The results demonstrated that the CoPSe catalyst exhibited the optimized 2e– ORR activity compared with CoP and CoSe. It disclosed an onset potential of 0.68 V and the H2O2 selectivity 76%-85% in a wide potential range (0-0.5 V). Notably, the CoPSe catalyst overcomes a significant challenge of a narrow-range selectivity for transition-metal based 2e– ORR catalysts. Finally, combining with electro-Fenton reaction, an on-site system was constructed for efficient degradation of organic pollutants. This work provides a promising non-precious Co-based electrocatalyst for the electrosynthesis of H2O2 in acidic media.