Turn-off luminescence sensing, white light emission and magnetic studies of two-dimensional lanthanide MOFs

, bpy and phen) increased the overall quantum yield (QY) of white light emission to 31% and 43%, respectively. The high QY observed for the Tb and Eu compounds was found to be sensitive and selective for the fluorometric detection of azinphos-methyl pesticide and trinitrophenol (TNP) in an aqueous medium at the ppb level. The same behaviour was observed when utilising the compounds as onsite paper strip sensors. Their magnetic properties were also studied, revealing for the Tb and Dy derivatives slow relaxation of the magnetisation at low temperature. The present study highlights the usefulness of rigid π-conjugated molecules such as 2,2'-bipyridine and 1,10-phenanthroline in enhancing the many utilities of rare-earth-containing MOFs towards white light emission, the sensing of harmful and dangerous substances and magnetic properties.