化学
立体选择性
催化作用
铜
组合化学
有机化学
药物化学
作者
Kelu Yan,Xiaoyu Wang,Jiangwei Wen,Qiuyun Li,Jianjing Yang,Xiaoyuan Tao,Shaobo Pan,Haosheng Liang,Xiu Wang
摘要
A copper-catalyzed anti -selective 1,2-silylamination of alkynes has been developed. This reaction combines the addition of silyl radicals to C–C triple bonds and further functionalization of vinyl radicals assisted by copper chelates.
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