Synthesis of high-performance NiO/ZnO composite for asymmetric supercapacitors

The electrode material's design and structure greatly influence supercapacitor efficacy. This study employed a novel 2-step hydrothermal and calcination approach to synthesize NiO/ZnO composites with a hierarchical microflower-wrapped spherical structure. The effect of varying the Ni/Zn ratio was systematically investigated, and the optimized NiO/ZnO-3 electrode exhibited excellent electrochemical properties, including a low equivalent series resistance (R s ) of 0.73 Ω, a minimal charge-transfer resistance (R ct ) of 0.55 Ω, and a specific capacitance of 243 F g −1 at 1 A g −1 . The electrode exhibited excellent cycling stability, retaining 87.2% of its capacitance after 5000 cycles at 15 A g⁻¹. The NiO/ZnO-3//AC asymmetric supercapacitor achieved 28.4 Wh kg⁻¹ energy density at 1170.1 W kg⁻¹ power density, retaining 114.8% capacitance after 10,000 cycles. This work highlights the synergistic effect of NiO/ZnO composites and introduces a scalable, cost-effective synthesis strategy that improves cycling stability and recyclability, advancing next-generation energy storage systems. • A novel 2-step hydrothermal method and calcination process were employed. • NiO/ZnO-3//AC exhibits excellent energy density and power density. • Novel electrode preparation process enhances the cycling stability of the device. • Novel process offers insights for future mass production and separator recycling.