Oriented Assembly of 2D Metal‐Pyridylporphyrinic Framework to Regulate the Redox Kinetics in Li−S Batteries

at 0.2 C. The capacity decay rate is only 0.0442% per cycle after 1000 cycles at 2 C. This work achieves the rational control of the central Co d electron state through the peripheral regulation and enriches the application of MOFs in accelerating the redox kinetics in Li-S batteries.