One-step rapid synthesis of Ni0.5Co0.5-CPO-27 nanorod array with oxygen vacancies based on DBD microplasma: As an effective non-enzymatic glucose sensor for beverage and human serum

The rational design of high-efficiency catalysts for non-enzymatic glucose sensing is extremely important for the timely and effective monitoring of glucose content in beverages and human blood. A 3D bimetallic organic framework (Coordination Polymer of Oslo, CPO) nanorod array with oxygen vacancies was green fabricated on carbon cloth (Ni0.5Co0.5-CPO-27 NRA/CC) using dielectric barrier discharge (DBD) microplasma for the first time. Density functional theory (DFT) calculations demonstrated that the oxygen vacancy of Ni0.5Co0.5-CPO-27 can be effectively induced under DBD microplasma conditions. Based on the 3D nanorod arrays with rich oxygen vacancies and bimetallic synergistic effects, as a non-enzyme glucose sensor, the Ni0.5Co0.5-CPO-27 electrode exhibited a sensitivity of 8499.5 μA L/mmol cm-2 and 3239.2 μA L/mmol cm-2 and a limit of detection (LOD) of 0.16 μmol/L (S/N = 3). It has been successfully applied to the determination of glucose levels in real samples such as cola, green tea and human serum.