电化学
共价键
四面体
铜
金属
化学
组合化学
结晶学
金属有机骨架
拓扑(电路)
材料科学
有机化学
电极
物理化学
数学
吸附
组合数学
作者
Zhenli Liu,Yan Shi,Qianrong Fang,Yaobing Wang,Daqiang Yuan
摘要
A three-dimensional metal-covalent organic framework (3D-MCOF) based on cyclic trinuclear units was synthesized using organic tetrahedral linkers and copper-based cyclic trinuclear complexes. The novel type of 3D-MCOF, named 3D-CTU-MCOF, with the ctn topology, is reported herein for the first time. Our study demonstrated enhanced electrocatalytic capacity for CO2 reduction reaction of 3D-CTU-MCOF compared to independent cyclic trinuclear units.
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