化学
荧光
异构化
离子
席夫碱
乙腈
光化学
核化学
立体化学
色谱法
有机化学
量子力学
物理
催化作用
作者
Dhanapal Jothi,Sathishkumar Munusamy,Sathish Sawminathan,Sathiyanarayanan Kulathu Iyer
出处
期刊:RSC Advances
[The Royal Society of Chemistry]
日期:2021-01-01
卷期号:11 (19): 11338-11346
被引量:21
摘要
A simple 1,8-naphthalimide based Schiff base probe (E)-6-((4-(diethylamino)-2-hydroxybenzylidene)amino)-2-(2-morpholinoethyl)-1H-benzo[de]isoquinoline-1,3(2H)-dione (NDSM) has been designed and synthesized for the specific detection of Fe3+ based on a fluorimetric mode. The absorbance of NDSM at 360 nm increased significantly in acetonitrile : water (7 : 3, v/v) medium only in the presence of Fe3+ ions with a visible colour change from yellow to golden yellow. Likewise, fluorescence emission intensity at 531 nm was almost wholly quenched in the presence of Fe3+. However, other competitive ions influenced insignificantly or did not affect the optical properties of NDSM. Lysosome targetability was expected from NDSM due to the installation of a basic morpholine unit. The LOD was found to be 0.8 μM with a response time of seconds. The fluorescence reversibility of NDSM + Fe3+ was established with complexing agent EDTA. Fe3+ influences the optical properties of NDSM by complexing with it, which blocks C[double bond, length as m-dash]N isomerization in addition to the ICT mechanism. The real-time application of Fe3+ was demonstrated in test paper-based detection, by the construction of a molecular logic gate, quantification of Fe3+ in water samples and fluorescence imaging of Fe3+.
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