Conjugated and Conducting Organic Polymers: The First 150 Years

Conductive organic polymers are most commonly generated from the oxidation or reduction of conjugated polymers. Although such conjugated polymers are typically viewed as modern materials, the earliest examples of these polymers date back to the early 19th century. The modern era of conjugated polymers began with the first reports of their conductive nature in the early 1960s. However, it was advances in the 1970s that brought particular focus to these materials with the first example of conductivity values in the metallic regime, for which the 2000 Nobel Prize in Chemistry was awarded to Hideki Shirakawa, Alan MacDiarmid, and Alan Heeger. Unfortunately, the historical narrative of these polymers is currently quite muddled in the primary literature, with various inaccuracies commonly propagated. In an effort to present a more accurate account as a resource for the field, the present report will review the first 150 years of the four primary parent polymers-polyaniline, polypyrrole, polyacetylene, and polythiophene, from their early origins in 1834 to their rapid development in the mid-1980s.