化学
组合化学
有机化学
苯衍生物
纳米技术
机制(生物学)
产量(工程)
化学合成
立体化学
催化作用
作者
Bingxue Xie,Zheng Wang,Yurou Huang,Sunmin Jiang,Tao Shen
摘要
-rich architectures using electrons as traceless reductants. Compared with classical dissolving-metal reductions, electrochemical approaches offer improved safety, tunability, chemoselectivity and functional-group tolerance. This review summarizes advances from 2019 to 2026, focusing on Birch-type electroreduction, electrochemical hydrogenation/deuteration and dearomative electroreductive coupling. Key developments, including rapid alternating polarity electrolysis, electrocatalytic hydride/deuteride transfer, radical-anion chemistry, Lewis acid activation and tandem C-C bond formation, are discussed. Remaining challenges and opportunities in asymmetric reactions, site selectivity, paired electrolysis and flow scale-up are also highlighted.
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