铟
双金属片
阴极
储能
硫化物
铜
化学
硫化铜
化学工程
材料科学
纳米技术
金属
光电子学
冶金
功率(物理)
物理
物理化学
量子力学
工程类
作者
Lin Chen,Jingwen Zhou,Junxiang Zhang,Guicai Qi,Bin Wang,Jianli Cheng
出处
期刊:Energy & environmental materials
日期:2023-02-20
卷期号:6 (5)
被引量:7
摘要
High energy density Li‐CO 2 batteries have attracted much attention owing to the “two birds with one stone” feature in fixing greenhouse gas CO 2 and providing renewable energy. However, poor reversibility of the discharge product Li 2 CO 3 is one of the main problems that limit its application, resulting in poor cycling stability and severe polarization. Herein, copper indium sulfide (CIS), a semiconducting non‐precious metal sulfide, is fabricated as cathode catalysts for high‐performance Li‐CO 2 batteries. Combined with the synergistic effect of bimetallic valence bonding and coordinated electron transfer, Li‐CO 2 batteries using CIS cathodes exhibit high full specific discharge capacity, excellent rate capability and cycle stability, namely it delivers a high specific full discharge capacity of 8878 μAh cm −2 , runs steadily from 10 to 100 μA cm −2 , and performs a stable long‐term cycling behavior (>1050 h) under a high energy efficiency of 84% and a low charge voltage of approximately 3.4 V at 20 μA cm −2 within 100 μAh cm −2 . In addition, a flexible Li‐CO 2 pouch cell is constructed to reveal the potential of employing CIS to fabricate flexible high energy storage devices in practical applications. This work shows a promising development pathway toward next‐generation sustainable energy storage devices.
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