Design, Synthesis, and Crystallization‐Induced Emission of Boron Difluorides β‐Ketoiminates

A series of new nitrogen-containing analogues of boron difluoride benzoylacetonates with hydrogen and methyl substituents at the nitrogen atom have been synthesized. A comparative study of boron difluoride β-ketoiminates and their oxygen-containing analogues by means of luminescence and IR spectroscopic methods as well as quantum chemistry simulations was also performed.