Surface enhanced infrared absorption (SEIRA) spectroscopy on nanoshell aggregate substrates

Abstract Aggregates of Au nanoshells on silicon substrates with plasmon resonances tuned to the infrared region of the spectrum provide a remarkably high-quality substrate for surface enhanced infrared absorption (SEIRA) spectroscopy. SEIRA spectra spanning the chemical fingerprint region of 700–3300 cm −1 with strong enhancement across this entire spectral range are obtained. SEIRA enhancement factors obtained for para- mercaptoaniline on these substrates are evaluated to be in the 10 4 range, based on a statistical evaluation of aggregate geometries combined with finite difference time domain modeling of the infrared ‘hot spots’ characteristic of the constituent structures.