碱性水电解
催化作用
电解
制氢
化学工程
电化学
氢
工艺工程
作者
Sengeni Anantharaj,Shubham Chatterjee,Karukkampalayam Chinnusamy Swaathini,Thangavel S. Amarnath,Elangovan Subhashini,Deepak K. Pattanayak,Subrata Kundu
标识
DOI:10.1021/acssuschemeng.7b03964
摘要
Sometimes, searching for a cost efficient bifunctional catalytic material for water splitting can be accomplished from a very unlikely place. In this work, we are reporting such a discovery of utilizing the stainless steel (SS) scrubber directly as a catalytic electrode for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) of water electrolysis in 1 M KOH. The iR corrected overpotential calculated at an areal current density of 10 mA cm–2 for a SS scrubber in HER is 315 mV which is 273 mV higher than Pt/C. Similarly, the SS scrubber required 418 mV at 10 mA cm–2 which is just 37 and 98 mV higher than Ni(OH)2 and RuO2. Interestingly, the kinetic analysis revealed that the SS scrubber had facile kinetics for both HER and OER in 1 M KOH as reflected by their corresponding Tafel slope values viz., 121 and 63 mV dec–1, respectively. In addition, the two electrode cell fabricated using the same SS scrubber electrode delivered 10 mA cm–2 at 1.98 V. Beyond everything, the SS scrubber had shown...
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