Pore Size Modulation in Flexible Metal‐Organic Framework Enabling High Performance Gas Sensing

Pore size plays a critical role in determining the performance of metal-organic frameworks (MOFs) in catalysis, sensing, and gas storage or separation. However, revealing the pore-size/property relationship remains extremely challenging because ideal structure models possessing different pore sizes but having the same components are lacking. In this work, a solvent-coordination directed structure swelling method was developed for modulating the ratio between the large and narrow pore phases of a flexible MOF, MIL-88B. Pore-size-dependent gas sensitivity and selectivity were studied for the first time in the MIL-88B samples. The optimized MIL-88B-20 % sample showed one of the best sensing performances among all the reported MOF-based H2 S-sensing materials. This work not only provides a method to synthesize ideal structure models for revealing the relationship between pore-size and properties, but also may inspire the development of high-performance gas sensing materials.