析氧
过电位
催化作用
X射线光电子能谱
化学
氧气
分解水
钙钛矿(结构)
无机化学
电解水
电解
化学工程
电化学
物理化学
结晶学
光催化
电极
有机化学
工程类
生物化学
电解质
作者
Tixuan Xia,Chunbo Liu,Yang Lü,Wei Jiang,Hongji Li,Yunchao Ma,Yuanyuan Wu,Bo Yu
标识
DOI:10.1016/j.apsusc.2022.154727
摘要
Oxygen evolution reaction is one of the core half-reactions in proton-exchange membrane (PEM) water electrolysis, but its slow reaction kinetics has been limiting the overall energy conversion efficiency (e.g., water splitting). It is urgent to develop efficient catalysts for OER in acidic media. At present, Ru-based catalysts have high activity, but their poor stability makes them difficult to be used in acidic oxygen evolution reactions. The involvement of lattice oxygen mechanism (LOM) in the reaction is one of the main causes of instability in Ru-based catalysts. Herein, we synthesized SrRu0.5Ir0.5O3 double perovskite by doping Ir into SrRuO3. The double perovskite displays an extraordinary OER performance with a low overpotential of 185 mV at 10 mA cm−2 current density and maintains its catalytic stability for over 50 h in 0.5 M H2SO4. X-ray photoelectron spectroscopy results show that the electronic synergistic effect between Ir and Ru enables the double perovskite materials with high activity. Meanwhile, the double perovskite catalyst inhibits the occurrence of the lattice oxygen mechanism during the OER, which greatly improve the catalytic stability of Ru-based perovskite materials.
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