H/F Substitution induced switchable coordination bonds in a cyano-bridged hybrid double perovskite ferroelastic

A three-dimensional cyano-bridged double perovskite ferroelastic [(CH₃)₃NCH₂F]₂[KFe(CN)₆] was constructed by introducing unprecedented switchable C-F-K coordination bonds. H/F substitution not only preserves the basic structure of the parent [(CH₃)₄N]₂[KFe(CN)₆] but also affords an m3̄mF2/m-type ferroelastic phase transition.