A Scalable BaTiO 3 Nanocoating Strategy for Cost‐Effective and Stable Sulfide‐Based All‐Solid‐State Batteries

S evolution and preserving conductivity after exposure. Combined experimental and finite element analyses reveal that the BTO layer homogenizes charge distribution, inhibits space-charge layer formation, and mitigates interfacial side reactions, leading to improved electrochemical and mechanical robustness. When paired with PCNCM83 cathodes, the modified electrolytes enable ASSBs with exceptional rate capability and ultralong cycling stability exceeding 10 000 cycles at 7 C. This universal nanocoating approach is compatible with various sulfide electrolytes and cathode chemistries, offering a viable pathway toward the scalable commercialization of high-performance solid-state batteries.