All‐Organic Superhydrophobic Coating Comprising Raspberry‐Like Particles and Fluorinated Polyurethane Prepared via Thiol‐Click Reaction

Mechanically robust superhydrophobic coatings have been extensively reported using chemically susceptible inorganic fillers like slica, titanium dioxide, and zinc oxide for constructing micro-nano structures. Organic particles are good candidates for improving chemical resistance, whereas the synthesis of organic particles with well-defined and stable micro-nano structures remains exclusive. Here, an all-organic, cross-linked superhydrophobic coating comprising raspberry-like fluorinated micro particles (RLFMP) and fluorinated polyurethane (FPU) is prepared via thiol-click reaction. Benefiting from the robust micro-nano structure of RLFMP and the excellent flexibility of FPU, the coating can maintain superhydrophobicity after severe alkali corrosion or mechanical damage, while the superhydrophobicity can be repaired readily by the fast recovery of micro-nano roughness and migration of branched fluoroalkyl chains to the coating surface. This design strategy is expected to provide a good application of thiol-click chemistry.