电致变色装置
电极
化学工程
小提琴手
光电子学
可见光谱
作者
Ruiting Yan,Lijun Liu,Hang Zhao,Yun Guang Zhu,Chuankun Jia,Ming Han,Qing Wang
摘要
A TCO (transparent conductive oxide)-free redox-flow electrochromic window (RFEW) with considerably improved performance is demonstrated. The new RFEW employs Prussian blue (PB)/Prussian white (PW) as the electrochromic (EC) material, in which the decoloration/coloration is achieved by the redox targeting reactions of anthraquinone-2,6-disulfonate (AQDS) and FeCl3 with PB/PW, respectively. These redox molecules are electrochemically oxidized/reduced in an external stack cell and circulated through the window cavity. Hence, the costly TCO glass, indispensable in conventional EC windows, becomes redundant in RFEWs. Owing to the fast charge transfer kinetics of AQDS and Fe3+, the RFEW design investigated in this study presents substantially reduced response time. For a window with a size exceeding 100 cm2, coloration/decoloration switching with a change in absorbance by more than 80% is achieved within approximately 2 min. The static and dynamic optical characteristics of the window pane and the electrochemical behavior of the stack cell were examined in detail to understand the operation of the RFEW.
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