荧光粉
材料科学
兴奋剂
光电子学
发光
分析化学(期刊)
猝灭(荧光)
晶体结构
光学
荧光
结晶学
物理
化学
色谱法
作者
Zhanglin Chen,Songmo Du,Kaiming Zhu,Zhaobo Tian,Jie Zhang,Fei Li,Shijia Zhang,Shuo Zhao,Wei Cui,Xuanyi Yuan,Kexin Chen,Guoliang Yuan,Guanghua Liu
标识
DOI:10.1021/acsami.3c03897
摘要
Multifunctional phosphors have significant application and scientific value and are becoming a research hotspot in the field of luminescent materials. Herein, we report Mn4+-activated double-perovskite-type Sr2LuNbO6 multifunctional phosphors with excellent comprehensive properties in the fields of optical temperature/pressure sensing and w-LED lighting. The crystalline structure, elemental composition, optimal doping concentration, crystal-field strength, and optical bandgap of the phosphors are investigated in detail, and the mechanisms of concentration and thermal quenching are discussed. From the optimal Sr2LuNb0.998O6:0.2%Mn4+ phosphor, a LED lamp for indoor warm-white lighting is successfully fabricated. Further, the thermometric properties of the phosphors are explored for applications as FIR- and lifetime-based thermometers, showing a maximum relative sensitivity of 1.55% K-1 at 519 K. Upon pressure loading, a significant red-shift of the peak centroid is observed, and the pressure sensitivity is determined to be 0.82 nm/GPa. These results suggest that the Mn4+-activated Sr2LuNbO6 multifunctional phosphors have great potential to be utilized in the fields of optical thermometry, manometry, and lighting.
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