Bionic Structural Coloration of Textiles Using the Synthetically Prepared Liquid Photonic Crystals

Abstract The structural coloration of textiles with bionic photonic crystals (PCs) is expected to become a critical approach to the ecological coloration of textiles. Rapid and large‐area preparation of PC structurally colored textiles can be achieved via self‐assembly of high mass fractions of liquid photonic crystals (LPCs). However, the rapid and large‐scale manufacturing of LPCs remains a challenge. In this work, the pH regulator is added in the process of emulsion polymerization to solve the problem of phase transformation caused by the thermal decomposition of the initiator to produce H + , directly achieving 40 wt.% PS nanospheres in the dispersion. Then oligomers and small‐molecule salts are removed from the system via dialysis, and the pre‐crystallized LPC system is efficiently prepared. Adjusting the particle size and the mass fraction of nanospheres is shown to be an efficient way to control the optical properties of LPCs. The rapid and large‐area preparation of PC structural color fabric and the patterned PC structural color fabric with an iridescent effect is implemented by using LPCs as the assembly intermediate. By constructing the encapsulation layer on the surface of the PC structural color fabric, the consistency of high structural stability and high color saturation of the PC is realized.