生物炭
吸附
四环素
复合数
生产(经济)
环境科学
环境化学
废物管理
制浆造纸工业
化学
环境工程
材料科学
复合材料
工程类
热解
宏观经济学
经济
有机化学
抗生素
生物化学
作者
Lei Ke,Lili Liu,Jiahong Zhang,Jing Fang,Shengdao Shan
出处
期刊:PubMed
[National Institutes of Health]
日期:2025-01-08
卷期号:46 (1): 272-281
标识
DOI:10.13227/j.hjkx.202312069
摘要
), the order of adsorption capacity of biochar for tetracycline was: perishable waste biochar > sludge biochar > peanut shell biochar. The aromaticity, hydrophobicity, and specific surface area of peanut shell biochar had important effects on its adsorption of tetracycline. The possible main adsorption mechanisms were π-π interaction, hydrophobicity, and pore filling. The specific surface area and pore volume of sludge biochar had a significant impact on its adsorption of tetracycline, and its possible main mechanisms included pore filling, surface complexation, and hydrogen bonding. The soluble organic carbon components and ash content of perishable waste biochar played a dominant role in its adsorption, with distribution being the main adsorption mechanism, followed by cation-π interaction and surface complexation. The effect of coexisting pollutants on the adsorption of tetracycline by biochar varied with the type of biochar. With the increase in ion strength and ammonia nitrogen concentration in the water, the adsorption capacity of peanut shell biochar for tetracycline showed a slight upward trend overall, whereas sludge biochar showed a slight downward trend. The adsorption of tetracycline on perishable waste biochar was not affected by ionic strength and ammonia nitrogen. Coexisting phosphates significantly reduced the adsorption efficiency of biochar for tetracycline, while coexisting aerobic organic compounds had no significant effect on the adsorption. The adsorption of tetracycline in water by sludge biochar and perishable waste biochar had good recyclable regeneration ability. The results of this study provide a reliable scientific basis and theoretical support for the engineering application of biochar in removing antibiotics from water.
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