化学
苯
金属有机骨架
多孔性
表征(材料科学)
结晶学
晶体结构
金属
化学工程
物理化学
纳米技术
有机化学
材料科学
吸附
工程类
作者
Hiroyasu Furukawa,Yong Bok Go,Nakeun Ko,Young Kwan Park,Fernando J. Uribe‐Romo,Jaheon Kim,Michael O’Keeffe,Omar M. Yaghi
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2011-08-15
卷期号:50 (18): 9147-9152
被引量:320
摘要
The concept and occurrence of isoreticular (same topology) series of metal-organic frameworks (MOFs) is reviewed. We describe the preparation, characterization, and crystal structures of three new MOFs that are isoreticular expansions of known materials with the tbo (Cu(3)(4,4',4''-(benzene-1,3,5-triyl-tris(benzene-4,1-diyl))tribenzoate)(2), MOF-399) and pto topologies (Cu(3)(4,4',4''-(benzene-1,3,5-triyl-tribenzoate)(2), MOF-143; Cu(3)(4,4',4''-(triazine-2,4,6-triyl-tris(benzene-4,1-diyl))tribenzoate)(2), MOF-388). One of these materials (MOF-399) has a unit cell volume 17 times larger than that of the first reported material isoreticular to it, and has the highest porosity (94%) and lowest density (0.126 g cm(-3)) of any MOFs reported to date.
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