Boosting the catalytic performance of metalloporphyrin-based covalent organic frameworks via coordination engineering for CO2 and O2 reduction

Coordination engineering is an effective strategy for improving the performance of Por-COFs in catalyzing CO 2 and O 2 electroreduction. Our computations suggest that Co–N 2 O 2 and Ni–N 2 S 2 coordinated Por-COFs could be potential candidates.