酞菁
材料科学
聚合物
电化学
选择性
电催化剂
多孔性
硝苯地平
导电聚合物
化学工程
纳米技术
多孔介质
金属有机骨架
再现性
电极
化学
有机化学
复合材料
色谱法
钙
物理化学
冶金
催化作用
吸附
工程类
作者
Yuxia Liu,Wensi Xu,Wenfeng Zhuge,Qing Huang,Gang Xiang,Jinyun Peng
标识
DOI:10.1016/j.snb.2023.135191
摘要
Metal phthalocyanine-based porous organic polymers have gained increasing attention in numerous areas, but their application potential has yet to be comprehensively explored. In this study, a planar polymer (AlPc-CC POP) with excellent electrochemical capabilities was prepared using a straightforward substitution method. The electrocatalytic activity of AlPc-CC POP towards nifedipine (NIF) was investigated using electrochemical analysis. Under optimal conditions, the electrochemical sensor response to NIF was linearly positively correlated at concentrations ranging from 0.04 to 50 μM with a detection threshold of 0.0273 μM. Moreover, the sensor performed well in terms of reproducibility, stability, and selectivity. Notably, the constructed sensing platform enabled the determination of NIF levels in pharmaceuticals and human sera. This work provides a generalized platform for the detection of antihypertensive NIF and validates the potential of phthalocyanine-based porous organic polymer for sensing.
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