Gas-responsive two-dimensional metal–organic framework composites for trace visualization of volatile organic compounds

Highly sensitive and specific identification of complex volatile organic compound mixtures has always been a huge challenge in the field of gas detection. To address this issue, the gas-responsive two-dimensional metal–organic framework (MOF) composites have been designed for fabricating a colorimetric sensor arrays for extremely sensitive detection of volatile organic compounds (VOCs). The physically exfoliated MOF nanosheets Zn2(bim)4 with large surface area and abundant unsaturated active sites were used for loading various dyes to form dye/Zn2(bim)4 composites. Due to the protective effect on dye activity and preconcentration for VOCs, the dye/Zn2(bim)4 composites-based colorimetric sensor arrays showed significantly enhanced sensitivity compared with the corresponding dyes for the detection of various VOCs. The mechanical flexibility of the dye/MOF nanosheets endowed the excellent film-forming properties on various substrates for fabricating the colorimetric sensor arrays. Besides owing to the hydrophobic property and the protection of the Zn2(bim)4 nanosheets, the dye/Zn2(bim)4 sensor arrays exhibited excellent anti-interference including humidity and temperature influence. On the basis of the fantastic properties of dye/Zn2(bim)4 composites for VOCs detection, the dye/Zn2(bim)4 sensor arrays were applied for the early perception of the plant disease late blight via ultra-sensitive and highly specific sensing the VOCs released from the infected plants.