Evaluation of the Solidification of Radioactive Wastes Using Blast Furnace Slag as a Solidifying Agent

The decommissioning process of nuclear power facilities renders hundreds of thousands of tons of various types of waste. Of these different waste types, the amount of concrete waste (CW) varies greatly depending on the type of facility, operating history, and regulation standards. From the previous decommissioning projects, CW was estimated to comprise 60-80 wt.% of the total weight of radioactive wastes. This represents a significant technical challenge to any decommissioning project. Furthermore, the disposal costs for the generated concrete wastes are a substantial part of the total budget for any decommissioning project. Thus, the development of technologies effective for the reduction and recycling of CW has become an urgent agenda globally. Blast furnace slag (BFS) is an industrial byproduct containing a sufficient amount (higher than 30%) of CaO and it can be used as a substitute for ordinary Portland cement (OPC). However, there have been few studies on the application of BFS for the treatment of radioactive waste from decommissioning processes. This study was conducted to evaluate the performance of the solidification agent using ground granulated BFS (SABFS) to pack radioactive wastes, such as the coarse aggregates of CW (CACW), waste soil (WS), and metal waste (MW). The analytical results indicated that the CaO content of the ground granulated BFS was 36.8% and it was confirmed that calcium silicate hydrate (CSH) could be activated as the precursor of the hydration reactions. In addition, the optimum water-to-binder ratio was determined to be 0.25 and Ca(OH)₂ and CaSO₄ were found to be the most effective alkaline and sulfate activators for improving the compressive strength of the SABFS. The maximum packing capacities of the SABFS were determined to be 9 and 13 wt.% for WC and WM, respectively, when the content of CW was fixed at 50 wt.%. The results of the leaching tests using SABFS containing radioactive wastes contaminated with Co, Cs, and Sr indicated that their leachability indices met the acceptance level for disposal. Consequently, the SABFS can be used as a solidifying agent for the safe disposal of radioactive waste.