A novel viologen-based hybrid crystalline material for photochromic glass films, information storage and anti-counterfeiting

Information storage and anti-counterfeiting are two very important applications of photochromic materials. Photochromic materials with both information storage and anti-counterfeiting should meet the requirements including fast coloration, good stability and reversibility, low storage cost, and practical application value. Herein, a novel viologen-based coordination polymer, Cd[(pbpy)_0.5(HBTC)Cl]·2H₂O (1) (pbpy = 1,1'-[1,4-phenylenebis-(methylene)]bis(4,4'-bipyridinium); HBTC^2- = 1,3,5-benzenetricarboxylic acid), has been constructed. Compound 1 not only exhibits selective amine sensing properties, but also shows excellent photochromic properties, and the anti-counterfeiting of a two-dimensional code can be also realized through the color-changing behavior. Meanwhile, photochromic glass films of compound 1 were prepared, and compared to traditional optical information storage technology, these photochromic glass films have better water resistance and stability, improving their practical application stability. This work has further enriched the application of photochromic materials in the field of sensing, anti-counterfeiting and information storage.