吸附
膜
化学
水溶液
单层
接触角
傅里叶变换红外光谱
分析化学(期刊)
化学工程
扫描电子显微镜
化学吸附
色谱法
核化学
无机化学
材料科学
有机化学
生物化学
工程类
复合材料
作者
Minjuan Chen,Jianxian Zeng,Zhenwei Wu,Rui Zhang,Zhengqiu Yuan,Xiaoping Huang,Kai Jin,Shengkai Yang,Yahong Li
摘要
Abstract BACKGROUND Developing new materials for separating Sr 2+ ions from aqueous solutions is significant. Metal–organic frameworks are regarded as excellent adsorption materials due to their high specific surface area and abundant adsorption sites. In this work, a novel UiO‐66‐(COOH) 2 ‐based mixed matrix membrane (MMM) was prepared by combining UiO‐66‐(COOH) 2 with polyethersulfone (PES) for separating Sr 2+ . RESULTS The MMMs were characterized using scanning electron microscopy, Fourier transform infrared spectroscopy and water contact angle and water flux measurements. Various contents (0–2.5 wt%) of UiO‐66‐(COOH) 2 were blended into PES membranes. The results showed that incorporating UiO‐66‐(COOH) 2 significantly increased membrane porosity and water flux, and reduced contact angle. The membrane (M4) that contained 2.0 wt% UiO‐66‐(COOH) 2 exhibited an excellent morphology and the highest Sr 2+ uptake capacity (111.9 μg cm −2 ). Adsorption kinetics and isotherms showed that the nature of the adsorption of the membrane towards Sr 2+ was chemisorption, homogeneous and monolayer. Compared with the adsorption capacity of UiO‐66‐(COOH) 2 towards Sr 2+ in adsorption packed column, these values of M4 decreased by about 75% during membrane filtration. The rejection performance of MMMs increased with increasing UiO‐66‐(COOH) 2 content. Breakthrough curves of MMMs were not correlated with flow rate in the range of 10–180 mL h −1 . The presence of Ca 2+ and Mg 2+ ions did not obviously affect the separation of Sr 2+ , but Pb 2+ had a significant influence. Furthermore, after five adsorption–desorption experiments, the regeneration remained at about 95% of initial values. CONCLUSIONS The MMMs showed good adsorption capacity for Sr 2+ and exhibited favorable reusability and stability. © 2023 Society of Chemical Industry (SCI).
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