Simultaneous Lattice Engineering and Defect Control via Cadmium Incorporation for High‐Performance Inorganic Perovskite Solar Cells

, which is found to reduce non-radiative recombination. These effects result in prolonged charge carrier lifetime, suppressed defect formation, decreased GBs, and an upward shift of energybands in the Cd-containing film. A champion efficiency of 20.8% is achieved for Cd-incorporated PSCs, together with improved device ambient stability. This work highlights the importance of simultaneous lattice engineering, defectcontrol and atomic-level characterization in achieving high-performance inorganic PSCs with well-defined structure-property relationships.