超级电容器
多孔性
材料科学
能量密度
向日葵
碳纤维
纳米技术
复合材料
化学工程
电容
工程物理
工程类
电极
化学
复合数
数学
组合数学
物理化学
作者
Mengna Zhang,Yunbin Pu,Yipu Xu,Xin Wang,Nan Xu,Tianyu Hou,Hui Peng,Guofu Ma
标识
DOI:10.1016/j.est.2022.105984
摘要
Herein, sunflower plate-derived nitrogen-doped porous carbon framework (SPPC) has been prepared by a one-step self-foaming and nitrogen doping strategy with sodium bicarbonate (NaHCO 3 ) as an activator and melamine as a nitrogen source. According to the self-foaming activation and abundant nitrogen doping effect produced by the thermal decomposition of NaHCO 3 and melamine, the typical SPPC-SM material exhibits a well-developed porous carbon skeleton structure, high specific surface area and high nitrogen content (8.35 wt%), which significantly enhances the electrochemical properties. The symmetrical supercapacitor constructed by the SPPC-SM and 0.5 M Na 2 SO 4 aqueous electrolyte has a wide and stable voltage window of 2 V, high energy density of 19.18 Wh kg −1 at a power density of 100.1 W kg −1 . In addition, the supercapacitor constructed by the SPPC-SM and ionic liquid (EMIMBF 4 ) electrolyte delivers ultra-wide operating voltage of 4 V and shows the high energy density of 74.04 Wh kg −1 at the power density of 400.1 W kg −1 , as well as a superior stability with capacitance retention of 87.1 % after 30,000 cycles. The green preparation of biomass-based nitrogen-doped porous carbon frameworks presented in this work provides a promising strategy for realizing wide operating voltage and high energy density supercapacitors. • Bread-inspired self-foaming strategy is used to fabricate porous carbon framework • Sodium bicarbonate is employed as dual functions carbonization assisted medium. • SPPC demonstrates a 3D honeycomb-like carbon framework structure. • Supercapacitor based on SPPC carries ultrahigh output voltage and high energy density.
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