Graphitic carbons: preparation, characterization, and application on K‐ion batteries

Abstract K‐ion batteries (KIBs) have drawn much attention due to the abundant potassium reserves and wide accessibility as well as high energy density, which can be designed for large‐scale energy storage systems. As the most promising anode materials for KIBs, graphitic carbons, especially those with an intermediate structure between the crystalline graphite and amorphous carbons become a hot research focus because of the improved rate capability and enhanced diffusion‐controlled capacity at low voltage regions. Herein, we first review the structures of graphitic carbons in the view of graphitic domains and the structure changes in their K‐ion intercalation compounds. Then, we summarize the preparation mechanisms and characterizations of graphitic carbons and the influence factors in their degree of graphitization. Furtherly, we illustrate the strategies to optimize their K‐ion storage properties from four aspects, namely graphitic domain design, microstructure engineering, electrochemical active component regulation, and defect engineering. Finally, we propose the issues that urgently need to be solved in graphitic carbons and the possible solutions. We hope that this view could offer some inspiration for the further designing and optimizing of graphitic carbons for practical KIBs.